Three-layered absorptive glass mat separator with membrane for application in valve-regulated lead-acid batteries

摘要

During charge and discharge of the lead-acid cell equal amounts of H_2SO_4 participate in the reactions at the two types of plates (electrodes). However, the charge and discharge reactions at the positive plates involve also 2mol of water per every mole of reacted PbO_2. Consequently, a concentration difference appears in the electrolyte between the two electrodes (horizontal stratification), which affects the reversibility of the processes at the two electrodes and thus the cycle life of the battery. The present paper proposes the use of a three-layered absorptive glass mat (AGM) separator, the middle layer playing the role of a membrane that divides (separates) the anodic and cathodic electrolyte spaces, and controls the exchange rates of H_2SO_4, H+ ions. O_2 and H_2O flows between the two electrode spaces. To be able to perform this membrane function, the thinner middle AGM layer (0.2 mm) is processed with an appropriate polymeric emulsion to acquire balanced hydrophobic/hydrophilic properties, which sustain constant H_2SO_4 concentration in the two electrode spaces during cycling. Three types of polymeric emulsions have been used for treatment of the membrane: (a) polyvinylpyrollidonestyrene (MPVS), (b) polyvinylpyrrolidone "Luviskol" (MPVP), or (c) polytetrafluorethylene modified with Luviskol (MMAGM). It is established experimentally that the MMAGM membrane maintains equal acid concentration in the anodic and cathodic spaces (no horizontal stratification) during battery cycling and hence ensures longer cycle life performance.