Polymer electrolyte membranes containing titanate nanotubes for elevated temperature fuel cells under low relative humidity

摘要

Nafion-titanate nanotubes composite membranes prepared through casting process have been investigated as electrolytes for polymer electrolyte membrane fuel cell applications under low relative humidity. The glass transition temperature and the decomposition temperature of composite membrane at dry state are higher than those of pristine Nafion membrane. Cracks have been observed in the membrane at the concentration of nanotubes above 5 wt.%. The maximum proton conductivity at 100 C and 50% relative humidity is observed with the concentration of doped titanate nanotubes of 5 wt.%. Solid nuclear magnetic resonance spectrum is applied to qualitatively characterize the status of water inside the membrane at different temperatures. The power densities at 0.8 V for cell assembled from composite membrane containing 5 wt.% of titanate nanotubes are about 13% and 35% higher than that for plain Nafion cells under 50% relative humidity at 65 °C and 90 °C, respectively.