Preparation of bulk-like La_(0.8)Sr_(0.2)Ga_(0.8)Mg_(0.2)O_(3-δ) coatings for porous metal-supported solid oxide fuel cells via plasma spraying at increased particle temperatures

摘要

While porous metal-supported solid fuel oxide cells (PMS-SOFCs) have the potential to decrease the cost and increase the start-up speed of power units, the available fabrication processes remain too cumbersome for industrial production. In this study, we prepared bulk-like strontium and magnesium-doped lanthanum gallate (LSGM) coatings using atmospheric plasma spraying (APS) at an increased particle temperature. The large equiaxed grains inside the coatings indicated the epitaxial growth of the splat interfaces and improvement in the coating quality. With increased particle temperature, the conductivity of dense LSGM coatings directly deposited by APS was comparable to that of the bulk material, and cell performance was also significantly enhanced. The maximum power density of the PMS-SOFC at 700 degrees C was 831mWcm(-2) and 596mWcm(-2) when high and low particle temperatures were used, respectively. These results indicated that the quality of the coating was improved by increasing the in-flight particle temperature. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.