Product analysis of catalytic multi-stage hydropyrolysis of lignite

摘要

A lignite added with 0.2% MoS_2 as catalyst was pyrolyzed under H_2 using multi-stage heating method (MHyPy) which means holding a suitable time near the peak temperature. The product distribution and detailed analysis of products were performed. The results show that the tar yield increased to 63.9% during MHyPy compared with that of 51.8% in traditional hydropyrolysis (HyPy), while the gas yield decreased to a half. This suggests the effective utilization of hydrogen during MHyPy. The light aromatics in the tar from MHyPy increased remarkably 42, 37.8 and 115.4% for BTX, PCX and naphthalenes, respectively. Biphenyls were also observed in the tar from MHyPy, which indicated the effective hydrogenation occurs during catalytic MHyPy. The rich pore structure of the char from MHyPy hints its high reactivity in the subsequent conversion process such as gasification and combustion.