Mobilization of Manufactured Gas Plant Tar with Alkaline Flushing Solutions

摘要

This experimental study investigates the use of alkaline and alkaline-polymer solutions for the mobilization of former manufactured gas plant (FMGP) tars. Tar-aqueous interracial tensions (IFTs) and contact angles were measured, and column Bushing experiments were conducted, NaOH solutions (0.01-1 wt.%) were found to significantly reduce tar-aqueous IFT. Contact angles indicated a shift to strongly water-wet, then to tar-wet conditions as NaOH concentration increased. Column experiments were conducted wkh flushing solutions containing 0.2,035, and 0.5% NaOH bom with and without xanrhan gum (XG). Between 10 and 44% of the residual tar was removed by solutions containing only NaOH, while solutions containing both NaOH and XG removed 81-9396 of the tar with final tar saturations as low as 0.018. The mechanism responsible for the tar removal is likely a combination of reduced IFT, a favorable viscosity ratio, and tar bank formation. Such an approach may have practical applications and would be significantly less expensive than surfactant-based methods.