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Photochemistry of the Cloud Aqueous Phase A Review

机译:云水平的光化学阶段审查

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This review paper describes briefly the cloud aqueous phase composition and deeply its reactivity in the dark and mainly under solar radiation. The role of the main oxidants (hydrogen peroxide, nitrate radical, and hydroxyl radical) is presented with a focus on the hydroxyl radical, which drives the oxidation capacity during the day. Its sources in the aqueous phase, mainly through photochemical mechanisms with H2O2, iron complexes, or nitrate/nitrite ions, are presented in detail. The formation rate of hydroxyl radical and its steady state concentration evaluated by different authors are listed and compared. Finally, a paragraph is also dedicated to the sinks and the reactivity of the HO? radical with the main compounds found in the cloud aqueous phase. This review presents an assessment of the reactivity in the cloud aqueous phase and shows the significant potential impact that this medium can have on the chemistry of the atmosphere and more generally on the climate.
机译:本文简要介绍了云水相的组成,并深入地在黑暗中深入,主要是在太阳辐射下。主要氧化剂(过氧化氢,硝酸盐基团和羟基)的作用在羟基自由基上呈现给聚焦,这在白天推动氧化能力。其在水相中的来源,主要通过与H 2 O 2,铁络合物或硝酸盐/亚硝酸盐离子的光化学机制进行详细介绍。列出了不同作者评估的羟基自由基的形成率及其稳态浓度。最后,段落也致力于沉积物和何的反应性?具有在云水相中发现的主要化合物的激进。本综述提出了对云水相中反应性的评估,并显示了这种培养基可以对大气化学的显着潜在影响,更普遍地对气候。

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