Integrated CO₂ capture-fixation chemistry via interfacial ionic liquid catalyst in laminar gas/liquid flow

摘要

Simultaneous capture of carbon dioxide (CO₂) and its utilization with subsequent work-up would significantly enhance the competitiveness of CO₂-based sustainable chemistry over petroleum-based chemistry. Here we report an interfacial catalytic reaction platform for an integrated autonomous process of simultaneously capturing/fixing CO₂ in gas–liquid laminar flow with subsequently providing a work-up step. The continuous-flow microreactor has built-in silicon nanowires (SiNWs) with immobilized ionic liquid catalysts on tips of cone-shaped nanowire bundles. Because of the superamphiphobic SiNWs, a stable gas–liquid interface maintains between liquid flow of organoamines in upper part and gas flow of CO₂ in bottom part of channel. The intimate and direct contact of the binary reagents leads to enhanced mass transfer and facilitating reactions. The autonomous integrated platform produces and isolates 2-oxazolidinones and quinazolines-2,4(1 H ,3 H )-diones with 81–97% yields under mild conditions. The platform would enable direct CO₂ utilization to produce high-valued specialty chemicals from flue gases without pre-separation and work-up steps.