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Models for Calcium Carbonate Precipitation in the Near-Well Zone by Degassing of CO2

机译:CO2脱气在近井带碳酸钙沉淀的模型

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Calcium carbonate scale formation is a well known problem for water producing wells. Although there are several types of scale forming processes, we investigate the case of calcium carbonate precipitation when the degassing of CO2 causes the calcium equilibrium concentration to decrease towards a production well. We study a simplified system of carbonate chemistry, which allows for analytical expressions for the porosity loss as a function of time. The precipitation process normally goes from flow-limited away from the well to precipitation-limited close to the well. We derive an expression that estimates the transition zone between these two regimes. Furthermore, we present analytical estimates for the porosity reduction at a given radius as a function of time, including an estimate for each of these precipitation regimes. These analytical results are tested against numerical solutions for the porosity loss, which account for the full set of equations of the model. The analytical models give an accurate estimate of the linear porosity reduction with time, until at least half the porosity is lost. Examples of scale formation are given for the two regimes. Reasonable values for the precipitation kinetics indicate that most production operations have a kinetics-limited regime close to the well. The models also show that this type of scale formation takes place very close to the wells, typically within a few well radii from the walls of the well.
机译:碳酸钙结垢的形成是产水井的众所周知的问题。尽管有多种类型的水垢形成过程,但我们调查了当CO2脱气导致钙平衡​​浓度朝生产井方向降低时碳酸钙沉淀的情况。我们研究了碳酸盐化学的简化系统,该系统允许以孔隙度作为时间函数的分析表达式。沉淀过程通常从远离井的流量受限到靠近井的降水受限。我们推导出一个表达式,用于估计这两个制度之间的过渡区域。此外,我们给出了给定半径下孔隙率降低随时间变化的分析估计,包括对每种降水方式的估计。这些分析结果针对孔隙度损失的数值解决方案进行了测试,这些解决方案说明了模型的所有方程式。分析模型给出了线性孔隙率随时间降低的准确估计,直到损失至少一半的孔隙率为止。给出了两种方案的水垢形成实例。沉淀动力学的合理值表明,大多数生产操作都在靠近井的位置进行动力学限制。这些模型还表明,这种水垢的形成非常靠近井,通常在距井壁几个井半径内。

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