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Source of condensate oil in the middle of southern margin, Junggar Basin, NW China

机译:中国西北部准gar尔盆地南缘中部的凝析油来源

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Through detailed geochemical analysis of over 40 crude oil, condensate oil and heavy oil samples in the southern margin of Junggar Basin, and based on the hydrocarbon generation condition of five sets of source rocks, with the combination between compositions of carbon isotopes of whole oil, light hydrocarbon, n-alkanes isoprenoids and biomarker composition characteristics, a detailed discussion on the source of the condensate oil in anticlines in the central part of the southern margin was carried out. Condensate oils from the central part of the southern margin have abundant isoprenoids, Pr/Ph<1.0. Carbon isotopes of whole oil are low with δ13C value between ?27‰ and ?28‰. The δ 13C value of alkanes with carbon number smaller than 9 ranges from ?26‰ to ?24‰, carbon isotopes of C9+ n-alkanes decrease remarkably with increasing carbon number, and the δ 13C value of C19+ n-alkanes is lower than ?30‰. The δ 13C value of pristane and phytane is lower than ?29‰. The biomarker components contain abundant C27 steranes and C30 methyl steranes, “V” shape distribution of C27, C28 and C29 20R sterane, abundant tricyclic terpanes with dominance of C21, and relatively high content of gammacerane with two isomers. The 20S/(20S+20R) ratio of C29 steranes is between 0.40 and 0.50, and the maturity calculated by the methylphenanthrene index and distribution fraction (R c) ranges from 0.70% to 1.1%. These geochemical characteristics of the condensate oils are very similar to those mature crude oils from the typical Cretaceous lacustrine source rocks in the central part of southern margin, but are greatly different from those of typical Jurassic crude oils, implying that these condensate oils are derived from mature Cretaceous lacustrine source rocks instead of highly mature Jurassic coal-measures source rocks.
机译:通过对准gar尔盆地南缘40多个原油,凝析油和重油样品进行详细的地球化学分析,并基于五套烃源岩的生烃条件,结合全油碳同位素组成,轻烃,正构烷烃类异戊二烯和生物标志物的组成特征,对南缘中部背斜线的凝析油来源进行了详细讨论。南缘中部的凝析油中富含类异戊二烯,Pr / Ph <1.0。全油的碳同位素较低,δ13C值在?27‰和?28‰之间。碳原子数小于9的烷烃的δ13C值在?26‰至?24‰之间,C9 +正烷烃的碳同位素随碳原子数的增加而显着降低,C19 +正构烷烃的δ13C值低于α。 30‰。 rist烷和植烷的δ13C值低于?29‰。生物标志物成分包含丰富的C27甾烷和C30甲基甾烷,C27,C28和C29 20R甾烷的“ V”形分布,具有C21优势的丰富的三环戊烷以及相对较高的具有两个异构体的γ-甘油。 C29甾烷的20S /(20S + 20R)比在0.40至0.50之间,通过甲基菲指数和分布分数(R c)计算得出的成熟度​​为0.70%至1.1%。凝析油的这些地球化学特征与南缘中部典型的白垩纪湖相烃源岩的成熟原油非常相似,但与典型的侏罗纪原油有很大的不同,这表明这些凝析油来自于成熟的白垩纪湖相烃源岩,而不是高度成熟的侏罗纪煤系烃源岩。

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