Precipitator concentration‑dependent opto‑structural properties of MgO nanoparticles fabricated using natural brine

摘要

In this paper, MgO nanoparticles (MNPs) were synthesized using simple wet chemical precipitation technique fromevaporative brine as Mg ions precursor. The effect of NaOH concentration on morpho-structural and optical propertiesof as-synthesized nanoparticles was studied. The obtained nanoparticles were characterized by X-ray Diffraction(XRD), transmission electron microscopy (TEM), field emission scanning electron microscope (FESEM), energy dispersiveX-ray (EDS), fourier transform infrared spectroscopy and UV–Vis absorption spectroscopy. The obtained structural properties(from XRD analysis) indicated that MNPs had pure cubic phase, high crystallinity, and average crystallite size and werein good agreement with TEM and FESEM characteristics. Also, increasing the concentration of the precipitator resultedin reduced crystallites size (from 37.09 to 17.61 nm), nanoparticles size (from 35–88 nm to 22–75 nm), and strain value(from 1.23 × 10~(–3) to 0.57 × 10~(–3)). The optical properties of MNPs including absorption (A), transmittance (T), absorptioncoefficient (α), optical band gap energy (E_g), Extinction coefficient (k), and refractive index (n) were investigated usingUV–Vis spectroscopy and examined in details.