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首页> 外文期刊>International Journal of Materials and Chemistry >Synthesis and Structural Characterization of (S)-Tetrahydro-Pyrrol-[1,2,c]-Imidazole-1,3-Dione
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Synthesis and Structural Characterization of (S)-Tetrahydro-Pyrrol-[1,2,c]-Imidazole-1,3-Dione

机译:(S)-四氢-吡咯-[1,2,c]-咪唑-1,3-二酮的合成及结构表征

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摘要

In this work we present the synthesis and X-ray single crystal structural characterization of the heterocyclic compound (S)-tetrahydro-pyrrol-[1,2,c]-imidazole-1,3-dione. This material crystallize in the orthorhombic system with space group P212121 (No19), Z=4, and unit cell parameters a = 7.136(1) ?, b = 8.009(2) ?, c = 11.378(2) ?. The molecular structure shows a hydantoin and pyrrolidine ring coupling forming a bicyclohydantoin. The crystal packing is governed by N--H···O hydrogen bond-type intermolecular interactions, forming infinite one-dimensional chains.
机译:在这项工作中,我们介绍了杂环化合物(S)-四氢-吡咯-[1,2,c]-咪唑-1,3-二酮的合成和X射线单晶结构表征。该材料在正交结构中以空间组P2 1 2 1 2 1 (No19),Z = 4和晶胞参数a结晶。 = 7.136(1)δ,b = 8.009(2)δ,c = 11.378(2)δ。分子结构显示乙内酰脲和吡咯烷环偶联形成双环乙内酰脲。晶体堆积受N·H··O氢键型分子间相互作用的控制,形成无限的一维链。

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