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TETRATIC PHASE IN THE PLANAR HARD SQUARE SYSTEM?

机译:平面硬方系统中的四相?

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System of hard squares in two dimensions (2D) has been studied by Monte Carlo simulations. The simulations indicate that the isotropic fluid phase in this system does not freeze into a 2D 'crystalline' phase (of square lattice and quasi-long-range translational order) but transforms into an intermediate phase with the quadratic quasi-long-range orientational order (of coupled molecular axes and intermolecular bonds) and the translational order decaying faster than algebraically. The equation of state and the specific heat of the system are surprisingly well reproduced by smoothed version of the free volume theory in the whole density range.
机译:蒙特卡洛模拟研究了二维(2D)的硬正方形系统。仿真表明,该系统中的各向同性流体相不会冻结成(方格和准远距离平移阶的)二维“结晶”相,而是转变为具有二次准远距离定向序的中间相(具有耦合的分子轴和分子间键)和翻译顺序的衰减速度快于代数。令人惊讶的是,在整个密度范围内,自由体积理论的平滑形式很好地重现了系统的状态方程和比热。

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