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Cerium tartrate as a corrosion inhibitor for AA 2024-T3

机译:酒石酸铈作为AA 2024-T3的缓蚀剂

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摘要

A new corrosion inhibitor, cerium tartrate, was synthetized. The inhibition behavior of cerium tartrate for 2024-T3 aluminum alloy was investigated in 0.05 M NaCl solution. The immersion tests indicate that the corrosion of Al2CuMg phase was well inhibited. The electrochemical results show that both anodic and cathodic inhibitions are present during the corrosion process. The surface characterizations reveal that the protective film of cerium tartrate inhibits the dealloying of Al2CuMg phase in the initial stage, and then cerium ions transform to cerium oxide/ hydroxides and appear at the Al2CuMg phase, blocking the further corrosion at those corrosion sites. (C) 2015 Elsevier Ltd. All rights reserved.
机译:合成了新型缓蚀剂酒石酸铈。在0.05 M NaCl溶液中研究了酒石酸铈对2024-T3铝合金的抑制行为。浸没测试表明,Al2CuMg相的腐蚀得到了很好的抑制。电化学结果表明在腐蚀过程中同时存在阳极和阴极抑制。表面表征表明,酒石酸铈的保护膜在初始阶段抑制了Al2CuMg相的脱合金,然后铈离子转变为氧化铈/氢氧化物并出现在Al2CuMg相中,从而阻止了在那些腐蚀部位的进一步腐蚀。 (C)2015 Elsevier Ltd.保留所有权利。

著录项

  • 来源
    《Corrosion science》 |2015年第6期|152-161|共10页
  • 作者单位

    Chinese Acad Sci, Inst Met Res, Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China|Northeastern Univ, Dept Chem, Shenyang 110019, Peoples R China|Shenyang Univ, Shenyang 110044, Peoples R China;

    Chinese Acad Sci, Inst Met Res, Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China;

    Chinese Acad Sci, Inst Met Res, Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China;

    Chinese Acad Sci, Inst Met Res, Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China;

    Northeastern Univ, Dept Chem, Shenyang 110019, Peoples R China;

    Chinese Acad Sci, Inst Met Res, Key Lab Nucl Mat & Safety Assessment, Shenyang 110016, Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Alloy; AFM; EIS; XPS; Neutral inhibition;

    机译:合金;原子力显微镜;EIS;XPS;中性抑制;

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