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The corrosion behavior of Ni-Cu gradient layer on the nickel aluminum- bronze (NAB) alloy

机译:Ni-Cu梯度层在镍铝青铜(NAB)合金上的腐蚀行为

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摘要

The gradient Ni-Cu layer on nickel aluminum-bronze alloy was obtained by the thermal diffusion process. The corrosion resistance was improved due to the formation of protective film, consisted of Ni(OH)(2) and Cu2O. Although the Ni-Cu layer exhibited local corrosion with uniform corrosion and pitting corrosion simultaneously during the immersion test, the pitting growth was depressed because of the gradient distribution of Ni and Cu. The relieving driving force for galvanic corrosion between outer passive layer and bare Ni-Cu in the pitting was the main factor, which was caused by the decreasing interface potential drop.
机译:通过热扩散过程获得了镍铝青铜合金上的梯度Ni-Cu层。由于形成了由Ni(OH)(2)和Cu2O组成的保护膜,耐蚀性得到了改善。尽管Ni-Cu层在浸没试验中同时表现出局部腐蚀,均匀腐蚀和点蚀,但由于Ni和Cu的梯度分布,点蚀的生长受到抑制。影响钝化层外部钝化层与裸露的Ni-Cu之间电偶腐蚀的缓解驱动力是主要因素,这是由于界面电势下降所引起的。

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  • 来源
    《Corrosion science》 |2018年第7期|8-19|共12页
  • 作者单位

    Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China;

    Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China;

    Tianjin Univ, Sch Mat Sci & Engn, Tianjin 300072, Peoples R China;

    Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China;

    Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China;

    Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Nickel-aluminum bronze alloy; Gradient Ni-Cu layer; Electrochemical calculation; XPS; SVET; Passive film;

    机译:镍铝青铜合金梯度镍铜层电化学计算XPS SVET钝化膜;

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