首页> 美国卫生研究院文献>ACS Omega >Synthesis and Characterization of Magnetic ZeoliteY–Palladium–Nickel Ferrite by Ultrasonic Irradiationand Investigating Its Catalytic Activity in Suzuki–MiyauraCross-Coupling Reactions
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Synthesis and Characterization of Magnetic ZeoliteY–Palladium–Nickel Ferrite by Ultrasonic Irradiationand Investigating Its Catalytic Activity in Suzuki–MiyauraCross-Coupling Reactions

机译:磁性沸石的合成与表征超声辐照Y-钯-镍铁氧体铃木-宫浦的合成及其催化活性的研究交叉偶联反应

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摘要

Zeolite faujasite is widely used as a catalyst in many industrial catalytic applications. In this study, synthesis and characterization of magnetic zeolite Y–palladium–nickel ferrite were studied. First, palladium nanoparticles were combined with nickel ferrite and then placed on zeolite Y by ultrasonic treatment. The structure and morphology of the synthesized magnetic zeolite Y–palladium–nickel ferrite were characterized using Fourier transform infrared, X-ray diffraction, scanning electron microscopy, transmission electron microscopy, energy-dispersive X-ray, vibrating sample magnetometer, and inductively coupled plasma optical emission spectroscopy analysis. Also, we investigated the catalytic activity of this prepared zeolite in Suzuki–Miyaura coupling reaction between phenylboronic acid and aryl halides. Our study shows that magnetic zeolite Y–palladium–nickel ferrite is a suitable catalyst for Suzuki–Miyaura coupling reaction. Short reaction time, high yield, and easy reusability are the advantages of using this catalyst in carbon–carbon cross-couplingreactions.
机译:沸石八面沸石在许多工业催化应用中被广泛用作催化剂。在这项研究中,研究了磁性沸石Y-钯-镍铁氧体的合成和表征。首先,将钯纳米颗粒与铁氧体镍混合,然后通过超声处理将其置于沸石Y上。利用傅立叶变换红外,X射线衍射,扫描电子显微镜,透射电子显微镜,能量色散X射线,振动样品磁强计和电感耦合等离子体对合成的Y-钯-镍铁磁沸石的结构和形貌进行了表征。光学发射光谱分析。同样,我们研究了这种制备的沸石在苯硼酸与芳基卤化物之间的Suzuki-Miyaura偶联反应中的催化活性。我们的研究表明,磁性沸石Y-钯-镍铁氧体是Suzuki-Miyaura偶联反应的合适催化剂。反应时间短,产率高和易于重复使用是在碳-碳交叉偶联中使用该催化剂的优势反应。

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