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Advances in Heterocatalysis by Nanomaterials

机译:纳米材料的杂化催化研究进展

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摘要

Heterogeneous catalysis played, plays, and will continue to play a major key role in industrial processes for the large-scale synthesis of commodity chemicals of global importance [ , ] and in catalytic systems that possess a critical role in energy generation [ , , , , , ] and environmental protection approaches [ , , , , ]. As a result of the ongoing progress in materials science, nanotechnology, and characterization methods, great advances have been currently recorded in heterogeneous catalysis by nanomaterials, the so-called “nanocatalysis” [ , , ]. Efficient approaches and advanced methods for the design of nanostructured composite materials (up to atomic level) [ , , , , ], subject to specific nanomorphologies with enhanced metal–metal and metal–support interactions that are favorable for catalysis (that enable fine-tuning of the critical physicochemical properties of the designed catalysts) [ ], provide optimized catalytic systems with outstanding performances in numerous eco-friendly and cost-effective applications. Under this line, great progress has been achieved in many applications of heterogeneous catalysis involving, for example, emissions control catalysis, waste treatment, photocatalytic, biorefinery, CO utilization, and fuel cells applications, as well as hydrocarbon processing for H , added-value chemicals, and liquid fuels production, among several others [ , , , , , , , , , , , , , , , , , ].
机译:在大规模生产具有全球重要性的商品化学品的工业过程中,以及在能源生产中发挥关键作用的催化体系中,非均相催化作用将继续发挥并将继续发挥重要作用。 ,]和环境保护方法[,,,]。由于材料科学,纳米技术和表征方法的不断进步,目前在纳米材料的非均相催化(即所谓的“纳米催化”)方面已取得了巨大的进步。设计纳米结构复合材料(直至原子水平)的有效方法和高级方法[,,,,],具有特定的纳米形态,具有增强的金属-金属和金属-载体相互作用,有利于催化(可进行微调)设计的催化剂的关键物理化学性质[],提供了优化的催化系统,在许多环保和具有成本效益的应用中均具有出色的性能。在此基础上,在多相催化的许多应用中已经取得了很大的进展,例如,排放控制催化,废物处理,光催化,生物精炼,CO利用和燃料电池应用,以及H的碳氢化合物处理,增加了价值。化学品和液体燃料生产,以及其他几种[,,,,,,,,,,,,,,,,。

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