Synthesis and Characterization of Novel Inorganic-Organic Hybrid Ru(II) Complexes and Their Application in Selective Hydrogenation

摘要

Novel Ru(II) complex-based hybrid inorganic-organic materials immobilized via a diamine co-ligand site instead of the conventional diphosphine ligand have been prepared. The complexes were prepared by two different methods: sol-gel and surface modification techniques. The structures of the desired materials were deduced by several available physical measurements like elemental analyses, infrared, FAB-MS and ¹H-, ¹³C- and ³¹P-NMR spectroscopy. Due to a lack of solubility the structures of xerogel >3 and modified >4 were studied by solid state ¹³C-, ²⁹Si- and ³¹P-NMR spectroscopy, infrared spectroscopy and EXAFS. These materials were stable enough to serve as hydrogenation catalysts. Selective hydrogenation of functionalized carbonyls in α,β-unsaturated compounds was successfully carried out under mild conditions in a basic medium using these complexes as catalysts.