QMS-01 adsorbent for removing methyl ethyl ketone and sec-butyl alcohol from hydrogen were developed and used for the purification of hydrogen in tail gas from methyl ethyl ketone unit. The commercial application results showed that using QMS-01 adsorbent,under appropriate conditions of tail gas space velocity in the range of 90-100 h-1 ,reaction pressure in the range of 2. 4-3. 0 Mpa and reaction temperature in the range of 5-10 °C ,the mass fraction of methyl ethyl ketone and sec-butyl alcohol in the tail gas could be both less than 1 μg/g. The purified hydrogen could well meet the requirements of hydrogen for hydrogenation processes, and the adsorbent could be regenerated having a service life of about 3-5 years.%开发用于脱除甲乙酮装置脱氢尾气中的微量甲乙酮和仲丁醇的QMS-01吸附剂,并在工业装置上进行工业应用.QMS-01吸附剂在脱氢尾气空速90～100 h-1、压力2.4～3.0 MPa、温度5～10℃的条件下,可使尾气中甲乙酮质量分数降至小于l μg/g、仲丁醇质量分数降至小于1μg/g.工业装置的应用结果表明,QMS-01吸附剂性能稳定,可操作范围宽,可使用3～5年,能满足工业装置的工艺要求.
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