主链螺旋聚甲基丙烯酸联萘酚单甲醚酯的合成

摘要

从1,1'联萘酚出发，合成得到了新型旋光性和非旋光性甲基丙烯酸酯聚合单体，并在AIBN的自由基引发作用下聚合得到了具有主链螺旋结构的新型旋光性聚合物。%The novel optically active and the corresponding optically inactive a- methylacrylate were successfully synthcsizcd with 1, 1' - binaphthols, andradically polym ierized to produce the optically active polymers.