Synthesis and Crystal Structure of N-Phenylbis(ferrocenecarboxyl)imide

摘要

The ferrocenyl compound, N-phenylbis(ferrocenecarboxyl)imide (C28H23NO2Fe2, Mr = 517.17), was synthesized and structurally characterized by means of X-ray single-crystal diffraction. It crystallizes in monoclinic, space group C2/c with a = 21.374(14), b = 10.430(7), c =10.741(7)(A), β= 114.184(8)°, V= 2184(2)(A)3, Z = 4, Dc = 1.573 g/cm3, F(000) = 1064,μ(MoKo) =1.355 mm-1, T= 291(2) K, the final R = 0.0548 and wR = 0.1437 for 1524 observed reflections with I ＞ 2σ(I). In this compound, the nitrogen atom links two ferrocenyl groups and one phenyl group forming a novel imido derivative.