首页> 中文期刊> 《结构化学》 >Synthesis and Crystal Structure of Bis(2-acetylpyridine thiosemicarbazonato)-indium(iii) Perchlorate Hydrate

Synthesis and Crystal Structure of Bis(2-acetylpyridine thiosemicarbazonato)-indium(iii) Perchlorate Hydrate

         

摘要

The title complex bis(2-acetylpyridine thiosemicarbazonato)-indium(iii) perchlo-rate hydrate has been synthesized by the reaction of 2-acetylpyridine thiosemicarbazide(L) with indium(iii) perchlorate,and its structure was characterized by elemental analysis,IR and single-crystal X-ray diffraction.The crystal of the title compound([In(C8H9N4S)2]ClO4·H2O) belongs to monoclinic,space group P21/c with a = 12.6438(18),b = 12.6259(18),c = 15.116(2) nm,β = 105.800(2)°,Z = 4,V = 2321.9(6) nm3,Mr = 618.79,Dc = 1.770 g/cm3,μ = 1.359 mm-1,F(000) = 1240,R = 0.0265 and wR = 0.0675.X-ray analysis indicates that various intriguing hydrogen patterns involving both the solvent intermedia and polyatomic counterions play crucial roles in the self-assembly of functional supramolecules.

著录项

  • 来源
    《结构化学》 |2011年第6期|882-886|共5页
  • 作者单位

    State Key Laboratory of Ceramic, Zibo Entry and Exit Inspection and Quarantine Bureau, Zibo 255031, China;

    Department of Medical Chemistry, Weifang Medical University, Weifang 261053, China;

    State Key Laboratory of Ceramic, Zibo Entry and Exit Inspection and Quarantine Bureau, Zibo 255031, China;

    State Key Laboratory of Ceramic, Zibo Entry and Exit Inspection and Quarantine Bureau, Zibo 255031, China;

    State Key Laboratory of Ceramic, Zibo Entry and Exit Inspection and Quarantine Bureau, Zibo 255031, China;

  • 原文格式 PDF
  • 正文语种 chi
  • 中图分类
  • 关键词

相似文献

  • 中文文献
  • 外文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号