首页> 中文期刊> 《结构化学》 >Synthesis, Crystal Structure and DNA Interaction of a Chiral Platinum(Ⅱ) Complex with 2-(2,3-Dimethoxy-phenyl)-1H-imidazo4,5-f 1,10 phenanthroline

Synthesis, Crystal Structure and DNA Interaction of a Chiral Platinum(Ⅱ) Complex with 2-(2,3-Dimethoxy-phenyl)-1H-imidazo4,5-f 1,10 phenanthroline

         

摘要

A new platinum(Ⅱ) complex of [Pt(chda)(2,3-dmopip)]C1-H2O (1,chda =cyclohexan-ediamine,2,3-dmopipH =2-(2,3-dimethoxyphenyl)-lH-imidazo[4,5-f][1,10]phenanthroline) has been synthesized by hydrothermal methods and characterized by elemental analysis,IR,single-crystal X-ray diffraction,UV-vis and fluorescent spectrum.In complex 1,the platinum adopts a four-coordinated square planar geometry.The DNA-binding interaction has been investigated.The complex can bind to DNA by an intercalative mode,presenting high DNA-binding affmity.

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  • 来源
    《结构化学》 |2017年第9期|1486-1492|共7页
  • 作者单位

    Guangxi Key Laboratory of Farm Products Processing(Cultivation Base);

    Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi;

    College of Chemistry and Food Science,Yulin Normal University,Yulin 537000,China;

    Guangxi Key Laboratory of Farm Products Processing(Cultivation Base);

    Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi;

    College of Chemistry and Food Science,Yulin Normal University,Yulin 537000,China;

    Guangxi Key Laboratory of Farm Products Processing(Cultivation Base);

    Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi;

    College of Chemistry and Food Science,Yulin Normal University,Yulin 537000,China;

    Guangxi Key Laboratory of Farm Products Processing(Cultivation Base);

    Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi;

    College of Chemistry and Food Science,Yulin Normal University,Yulin 537000,China;

    Guangxi Key Laboratory of Farm Products Processing(Cultivation Base);

    Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi;

    College of Chemistry and Food Science,Yulin Normal University,Yulin 537000,China;

    Guangxi Key Laboratory of Farm Products Processing(Cultivation Base);

    Colleges and Universities Key Laboratory for Efficient Use of Agricultural Resources in the Southeast of Guangxi;

    College of Chemistry and Food Science,Yulin Normal University,Yulin 537000,China;

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