<正> Mr=996.91, triclinic, P1, a=8.773(2), b=9.712(3), c=13.652(1) A; α=69.24(0), β=70.43(3), γ=66.87(l)°; Z=l, Dx=1.699 g/cm 3. Final R=0.053 for 3186 reflections with I≥3a(I). There is an interesting trans influence of μ-s bridge in this binuclear cluster. Mo-Mo distance is 2.752(1) A.
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机译:SYNTHESIS AND CHARACTERIZATION OF (2,4,6-TRIMETHYLPHENYLIMIDO)MOLYBDENUM COMPLEXES - X-RAY CRYSTAL STRUCTURES OF (L-OET)MO(NMES)(2)CL, (L-OET)MO(NMES)CL-2, AND MOCL3(NMES)(DEPE) (MES EQUALS 2,4,6-TRIMETHYLPHENYL, L-OET=(ETA-C5H5)CO(P(O)(OET)(2))(3),
机译:Diazo complexes of rhenium: Preparations and crystal structures of the bis(dinitrogen), Re(N-2)(2){PPh(OEt)(2)}(4)BPh4 and methyldiazenido ReCl(CH3N2)(CH3NHNH2){PPh(OEt)(2)}(3)BPh4 derivatives Review