首页> 中文期刊> 《结构化学》 >CRYSTAL STRUCTURE OF PYRIDINUM μ-OXO-μ-SULFATO-BIS(OXO(TRITHIOCYNATO)-MOLYBDAIE(V))

CRYSTAL STRUCTURE OF PYRIDINUM μ-OXO-μ-SULFATO-BIS(OXO(TRITHIOCYNATO)-MOLYBDAIE(V))

         

摘要

<正> Introduction. The structural characterization of the compounds of Mo with inorganicacid radical may be belpful to the elucidation of the role of Mo enzymes in the catalysis of oxyanions(NO3-/N02-,S04~2-/SO3~2-)~1 Their spectral properties have therefore been investigated. Trzebiatowska et al. believe that there are two complexing models with the bridging SO4~2-. One is that two Oxygen atoms in sulfate are bonded to two Mo atoms respectively whereas the Other is that theY are bonded to two Mo atoms simultaneously, forming a

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