THE STRUCTURE AND SYNTHESIS OF MoFe3S4（Etadtc）·5MeCN

摘要

＜正＞ INTRODUCTION. More and more models of active center were suggested with wide study on the MoFe-protain and FeMo-cofactor of nitrogenase. Most of them contain MFe3S3+4 （M=Mo,Fe） cubane-type core, so a great interest has been focused on the Studies of MoFe4, cubane-type compounds. The type species have been reported by holm et al. We have also made researches on the single cubane-like compounds. Here we describe the synthesis and structure of [MoFe3S4（Et2dtc）5MeCN （1）.