CRYSTAL STRUCTURE OF BIDN-t-BUTYLBUTEN-2-YLIDENE DICHLOROPALLADIUM（II）

摘要

＜正＞ The title compound, C15H30N2PdCl2 （Mr=427.73）, crystallizes in two kinds of crystal forms I and II.I : monoclinic, P21/c, a = 8.234（1）, b = 13.702（3）, c = 8.939（2） A, β = 93.90（1）°, V = 1010.55 A3, DC = 1.407g/cm3, R = 0.032 for 2098 observed reflections.II: triclinic, Pl, a=8.179（1）, b=8.182（1）. c=8.231（2） A, α=91.89（1）°, β=91.90（2）°, α=113.80（1）°, V =503.09A3, DC =1.413 g/cm3, R = 0.036 for 1770 observed reflections.The molecules in both crystals I and II possess the identical configurations but there are two orientations of molecules in the crystal II.