CRYSTAL STRUCTURE OF （Ph2Ppy）2 （μ-Cl）2Cu2Cl2

摘要

＜正＞ （Ph2Ppy）2（μ-Cl）2Cu2Cl2 （C34H28Cl4Cu2N2P2）: Mr=795.5, triclinic, Pl, a=13.891（2）, b= 13.196（3）, c= 20.158（4） A, d= 90.28（1）°, β=110.05（2）°, r= 90.13（1）°, Z=4, V= 3471.04A3, Dx=1.53 gcm-3, R=0.066, Rw= 0.076 for 5486 observed unique reflections. The complex was prepared by the reaction of （Ph2Ppy）2NiCl2 with CuC≡CPh in CH2Cl2 solution.