CRYSTAL STRUCTURE OF {Ni（C4H9O）2PS2(C12H8N2)2} -（C4H9O）2PS2

摘要

＜正＞ {Ni C（C4H9O）2PS2] （C12H8N2）2} [C（C4H9O）2PS2], Mr= 795. 60, Monocinic,P2,/n,a=16. 806（2）, b=12. 720（2）, c=21. 248（2） A. β=98. 454（7）°, V = 4493A3,Z=4,Dc= 1. 18g·cm-3,Mo Ka radiation,A=0. 71069A ,F（000） = 1664, R=0. 102 for 4154 reflections with I≥3σ（I）.The crystal structure consists of complex cation {NiC（C4H9O）2PS2]（C12H8N2）2}+ and complex anion C（C4H9O）2PS2]-. In the cation, nickel （Ⅱ） atom is coordinated by four nitrogen atoms and two sulfur atoms to form a distorted octahedron.