Synthesis and Application of Lanthanide Complexes with Schiff Base of Pridoxylidence-Glycine

摘要

A series of novel rare earths complexes with Schiff base of pridoxylidence-glycine acid (HL) were synthesized in absolute methanol under argon atmosphere. The complexes were characterized by elemental analysis, molar conductivity, IR, UV spectra, and H-NMR spectra et al. Data indicate that the complexes have a general formula Ln LCl 2·3H 2O (Ln=La, Y, Sm, Gd, Dy, Yb; L=C 10H 11N 2O 4). Effects of the complexes (Ln=La) on physiological and biochemical indexes of plants under Pb stress were studied. The experiments shown that the complexes obviously mitigated Pb pollution results in decreasing of chlorophyll content, rising of cell membrane permeability, changing catalase(CAT) and distribution of Pb.