首页> 中文期刊> 《中国炼油与石油化工(英文版)》 >Industrial Production of Catalyst for Removing Trace Olefins from Aromatics

Industrial Production of Catalyst for Removing Trace Olefins from Aromatics

         

摘要

A novel additive incorporated into the catalyst for removing trace olefins from aromatics was proposed, and under the laboratory conditions the lifetime of the catalyst was increased from 5 h to 8 h upon specifying the conversion of the olefins equating to more than 55% as a criterion. Catalyst production, which was named ROC, has been successfully scaled up from laboratory formulations to commercial scale manufacture and over 100 tons of catalyst had been produced. The superiority in catalytic activity was identified by the evaluation tests of the ROC catalyst based on whatever kind of feedstocks (with their bromine index ranging from 400 mgBr/100g to 1 200 mgBr/100g) being used as the feedstock. The X-ray diffraction patterns had verified that the additive was highly dispersed on the surface of catalyst; the GC-FID analysis results showed that the ROC catalyst could increase the xylene content; the pyridine-FTIR spectroscopic analyses suggested that the additive could increase the amount of the weak L acids, which was the main cause leading to enhancement of the catalyst activity.

著录项

  • 来源
    《中国炼油与石油化工(英文版)》 |2012年第2期|44-49|共6页
  • 作者

    Pu Xin; Shi Li;

  • 作者单位

    The State Key Laboratory of Chemical Engineering East China University of Science and Technology Shanghai 200237;

  • 原文格式 PDF
  • 正文语种 chi
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