双（氟代磺酰）亚胺及其盐的制备、性能与应用进展

摘要

双（氟代磺酰）亚胺及其盐具有独特的结构和性能,在锂二次电池、离子液体、催化剂等领域引起了广泛的关注。本文综述了该类化合物的制备方法,比较了各类方法的优缺点;从分子结构上分析了该类化合物某些碱金属盐含有结合水的原因,并归纳了目前合成无水型碱金属盐的方法;综述了它们作为锂二次电池的电解质使用时的各项性能;最后介绍了它们的应用进展,并指出了今后的研究重点及方向。%Due to their unique structure and performance,bis（fluoro-based sulfonyl）imides and their salts have attracted increasing interests in the fields of lithium-based rechargeable batteries,ionic liquids,and catalysts,et al.In this paper,preparation methods of these compounds are reviewed,and their advantages and disadvantages are compared.The reason of some alkali metal salts combined with hydration water is analyzed from their molecular structures,and preparation methods of anhydrous alkali-metal salts are also summarized.Their performance is introduced when they are used as electrolytes of lithium-based rechargeable batteries.At last,their application progress is presented,and the research emphases and development trend are discussed.