以淮北煤田二叠纪5、4煤层15个煤样品为研究对象,对样品在815℃下进行灰化,并采用等离子体原子发射光谱(ICP-AES)对煤灰中成分进行测定,采用X射线衍射(XRD)对原煤以及灰化后的样品中矿物质成分进行了分析.在此基础上,探讨了煤中矿物质种类及影响煤中矿物质的主要因素,分析了煤中矿物质在815℃灰化前后的变化特征.结果表明,煤中矿物质种类受多种因素影响,灰化过程中矿物质的种类、含量会发生改变,且部分矿物在高温作用下发生变化,重新组合,形成相对较稳定的新矿物,从而为今后煤灰的综合利用提供科学论据.%15 coal samples were collected from No. 5 and No. 4 Permian coal seams in the Huaibei coalfield, Anhui Province. Inductively coupled-plasma atomic-emission spectrometry (ICP-AES, VISTA-PRO, America Varian) was used to determine the major element composition of coal ash after the ashing of samples at 815℃ , and the minerals in raw coal and coal ash samples were investigated by X-ray diffraction (XRD, Cu, D/max-1200, Japan). Using these methods, the authors determined the major minerals and their relative abundances in coal and coal ashes. The results show that the major minerals in raw coals are smectite, illite, kaolinite, chlorite, quartz, calcite and dolomite. Pyrite was not detected on the XRD spectra because the coals are very low in sulfur (averagely 0.56%). New minerals including plagioclase and hematite were formed during the ashing process.
展开▼
