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TEXTURE ASPECTS OF DELAYED HYDRIDE CRACKING IN PRODUCTS FROM Zr-BASED ALLOYS

机译:Zr基合金产品中氢化物延迟裂解的纹理方面

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Delayed hydride cracking (DHC) in products from Zr-based alloys under tensile loading is considered as a texture-dependent phenomenon. DHC development is anisotropic due to crystallographically regulated operation of plastic deformation mechanisms within zones of stress concentration near moving cracks. As applied to both plain and notched samples from Zr-l%Nb sheet, it was shown by X-ray study, that α-Zr crystallites under tensile loading change their initial orientation in different manners by means of slip or twinning depending on the direction of this loading. Features of the plastic deformation zone at the tip of moving crack vary in accordance with operating mechanisms. The revealed regularities of local reorientation are valid in the case of DHC in channel CANDU tube from Zr-2.5%Nb alloy as well. The orientation of S-hydrides, observed near the fracture surface, testifies that they reprecipitate in α-Zr matrix both by its initial texture and after twinning. The proposed mechanism of DHC involves the twinning by {10.2} planes within the plastic deformation zone near the crack tip, formation of the distinct boundary between deformed and undeformed regions with the increased gradient of lattice distortion, the intense diffusion of hydrogen to this boundary, the preferential precipitation of stress-oriented hydrides at its favorably positioned sections, and the growth of hydrides both inside and outside the plastic deformation zone till the next step of the crack between boundaries, decorated by hydrides. The known anisotropy of DHC reflects variation of the capacity of the α-Zr matrix to deform by twinning depending on the direction of tensile loading.
机译:Zr基合金在拉伸载荷下产品中的延迟氢化物开裂(DHC)被认为是与纹理有关的现象。 DHC的发展是各向异性的,这是由于在移动裂缝附近的应力集中区域内塑性变形机制的晶体学调控操作。 X射线研究表明,应用于Zr-1%Nb片材的平样品和有缺口的样品时,α-Zr微晶在拉伸载荷下会根据方向的不同以滑动或孪晶的方式改变其初始取向这个负载。移动裂纹尖端处的塑性变形区的特征根据操作机制而变化。在通道CANDU管中的DHC由Zr-2.5%Nb合金制成的情况下,所揭示的局部重新定向规律也是有效的。在断裂表面附近观察到的S-氢化物的取向证明,无论是其初始织构还是孪生后,它们都在α-Zr基质中重新沉淀。提出的DHC机理涉及裂纹尖端附近塑性变形区内的{10.2}平面孪生,变形和未变形区域之间明显边界的形成以及晶格畸变梯度的增加,氢向该边界的强烈扩散,应力定向的氢化物在其有利位置处的优先析出,以及在塑性变形区域内外的氢化物的生长,直到边界之间的裂纹的下一步被氢化物装饰为止。 DHC的已知各向异性反映了α-Zr矩阵根据孪生载荷的方向通过孪晶变形的能力的变化。

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