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A comparison of analytical methods for oxygenated volatile organic compounds in ambient air

机译:环境空气中氧化性挥发性有机化合物分析方法的比较

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Three separate methods for analyzing oxygenerated volatile organic compounds in ambient air samples are compared and the appropriateness of each method in quantifyingspecific oxygenated VOCs is assessed. The first methd included in the comparision consists of a modified EPA Method TO-14, in which asample air is cryogenically trapped from plished-interior-surface s tainless steel canisters and analzed via high resolution gas chromatography with flame ionization detection. In the latter two methods, oxygenated VOCs in air samples are trapped onto multiadsorbent-bed tubes, trapped water is purged from the sorbent bed with intert gas, then the samples are analyzed by either GC/FTIR/MS or high resolution gas chromatography with flame ionization detection. The confounding effects of water present in samples are addressed for each of the methods in this study.
机译:比较了分析环境空气样品中含氧挥发性有机化合物的三种独立方法,并评估了每种方法在定量特定含氧挥发性有机化合物中的适用性。比较中包括的第一种方法是一种经过改进的EPA方法TO-14,其中将空气样品从已打磨的内表面不锈钢罐中低温捕集,并通过带有火焰电离检测的高分辨率气相色谱法进行分析。在后两种方法中,将空气样品中的氧化VOC捕集到多吸附剂床试管中,用惰性气体从吸附剂床中清除捕集的水,然后通过GC / FTIR / MS或带有火焰的高分辨率气相色谱分析样品电离检测。对于本研究中的每种方法,都解决了样品中水的混杂影响。

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