Rationalizing the Meaning of Coefficients in Flory-Huggins Approach to Polymer-Solvent Interactions

摘要

The Flory-Huggins interaction parameter for a polymer solution can be represented as the product of two functions, which separately take into account the effects of the polymer volume fraction and temperature. The latter factor contains three constants, usually viewed as best-fit coefficients. They are expressed in terms of two thermodynamic quantities, namely, the excess partial molar heat capacity of the solution and a reference temperature, thus allowing to guess their physical meaning. The formulae so obtained were tested with satisfactory results for two solutions of polystyrene in acetone and for two polymer blends (PC/PMMA and PS/PVME.) Furthermore, an attempt was made to calculate the above-mentioned reference temperature from data referring to the phases in solution.