Decreasing Iron Content in Phosphoric Acid

摘要

The major goal of this study is to decrease iron content in wet-process phosphoric acid. Reducing the amount of post-precipitated sludge in the acid is another important objective in this investigation. In order to achieve these goals, research efforts have focused on bench scale testing of an iron-chelating reagent to remove iron from phosphoric acid produced from South Florida high-iron and -magnesium phosphate concentrate, and plant testing using freshly produced concentrated acids for reducing the post-precipitated sludge. The data obtained in the above studies suggest that the addition point of the precipitating reagent is very important, as the precipitated iron compound has higher solubility at higher P_2O_5 concentrations. Up to 60% Fe_2O_3 removal efficiency is achieved depending on the amount of the reagent, concentration of acid used, and operating conditions. The addition of precipitating reagents to freshly concentrated phosphoric acid leads to a decrease of up to 84% in sludge volume percentage depending on acid type and clarification conditions. Decreasing the volume percentage of the sludge facilitates acid handling as well as decreases the adherent water-soluble P_2O_5 leading to lower total P_2O losses.