首页> 外文会议>China-Japan Symposium on Coal and C1 Chemistry; 20061022-28; Chengdu(CN) >THE INFLUENCING FACTORS OF CARBON DEPOSITION OF CATALYSTS
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THE INFLUENCING FACTORS OF CARBON DEPOSITION OF CATALYSTS

机译:催化剂碳沉积的影响因素

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Carbon deposition is one of the major causes of catalyst deactivation in the refroming reactions. The factors of atmosphere, temperature,catalysts play an important part in resistance deposition . The basic supporter always used as the carrier of anti-carbon deposition has been proved by researchers. Although it has been reported that supported noble and rare earth metal catalysts have promising catalytic performances and low sensitivies to carbon deposition, the expensive, finite and non-recycle limit their utilization. Carbon deposition can block the pore of catalysts, so we can enlarge the pore of the catalysts to prolong its lifetime or pretreat the catalyst active component with sulfuration. We considered that the researches of anti-carbon should also focus on the metal catalyzers. The active phase of carbon deposition is to reduce through the interaction of (SMSI) to resist carbon deposition. In a word, in order to meet the industrialized demand, a cheapness, high activity, high stability and better anti-carbon performance catalyst or coke inhibitor should be developed in the future.
机译:碳沉积是重整反应中催化剂失活的主要原因之一。气氛,温度,催化剂等因素在电阻沉积中起重要作用。研究人员证明了一直用作抗碳沉积载体的基本载体。尽管已经报道了负载的贵金属和稀土金属催化剂具有令人鼓舞的催化性能和对碳沉积的低敏感性,但是昂贵的,有限的和不可循环的限制了它们的利用。碳沉积会堵塞催化剂的孔,因此我们可以扩大催化剂的孔以延长其寿命或通过硫化对催化剂活性成分进行预处理。我们认为抗碳的研究也应集中在金属催化剂上。碳沉积的活性相是通过(SMSI)的相互作用来减少碳沉积而减少的。简而言之,为了满足工业化需求,将来应该开发廉价,高活性,高稳定性和更好的抗碳性能催化剂或焦炭抑制剂。

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